Description

• Title:
  Complex formation of fenchone with alpha-cyclodextrin: NMR titrations
• Creator:
  Nowakowski, Michał;
  Ejchart, Andrzej
• Description:
  13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with acyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two a-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by a-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid.
• Object availability:
  free access
• Date:
  2014
• Type:
  Article;
  PeerReviewed
• Language:
  English
• Format:
  application/pdf
• Publisher:
  Springer
• Relation: http://eprints.ibb.waw.pl/724 ;http://www.springer.com/chemistry/organic+chemistry/journal/10847 ;doi:10.1007/s10847-013-0356-4
• Subject:
  QD Chemistry
• Identifier: http://eprints.ibb.waw.pl/724/1/Ejchart.pdf ;
  Nowakowski, Michał and Ejchart, Andrzej (2014) Complex formation of fenchone with alpha-cyclodextrin: NMR titrations. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 79 . pp. 337-342. ISSN 1573-1111 (electronic version)
• Data provider:
  Repozytorium Instytutu Biochemii i Biofizyki Polskiej Akademii Nauk
• Can I use it?:
  seek permission
• Type:
  other